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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2015 Volume 25, Issue 3, Pages 188–190 (Mi mendc2345)

This article is cited in 16 papers

Communications

Regio- and stereoselective cycloaddition of stable azomethine imines to (arylmethylidene)malononitriles

M. I. Pleshcheva, N. V. Das Guptaa, M. I. Struchkovaa, A. S. Goloveshkinb, I. S. Bushmarinovb, D. V. Khakimova, N. N. Makhovaa

a N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: [3 + 2] Cycloaddition of 1-arylmethylidene-3-oxopyrazolidin-1-ium-2-ides (stable azomethine imines) to (arylmethylidene)malononitriles proceeds regio- and stereoselectively to afford 1,3-diaryl-5-oxotetrahydropyrazolo[1,2-a]pyrazole-2-carbonitriles that proved resistant to azomethine imines metathesis.

Language: English

DOI: 10.1016/j.mencom.2015.05.009



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