This article is cited in 7 papers

Communications

Efficient synthesis of tertiary acyclic amides by the Chapman rearrangement of aryl benzimidates in ionic liquids

M. A. Epishina^a, A. S. Kulikov^a, N. V. Ignat'ev^b, M. Schulte^b, N. N. Makhova<sup>a

a</sup> N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b Ionic Liquid Research Laboratory, Merck KGaA, Darmstadt, Germany

Abstract: The Chapman rearrangement of aryl N-arylbenzimidates to tertiary acyclic amides is accelerated in ionic liquids and proceeds at lower temperatures as 120–190°C.

Language: English

DOI: 10.1016/j.mencom.2015.03.016

Bibliographic databases:

•