This article is cited in 4 papers

Communications

Nitrosonium nitratometallates NO[M(NO₃)₃] (M = Co, Ni): new synthetic approach and crystal structures

E. B. Deeva, A. V. Merkulova, S. I. Troyanov, M. A. Zakharov, V. A. Tafeenko, V. F. Kozlovskii, I. V. Morozov

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Monoclinic and triclinic modifications of nitrosonium nitratonickelate NO[Ni(NO₃)₃] as well as triclinic modification of nitrosonium nitratocobaltate NO[Co(NO₃)₃] (isostructural to triclinic NO[Ni(NO₃)₃]) have been synthesized by a new synthetic approach. Single crystal XRD studies revealed the similarity of all these structures in which octahedrally coordinated metal atoms are connected through NO₃^- bridges forming three-dimensional distorted cubic framework with NO⁺ cations located in the framework cavities.

Language: English

DOI: 10.1016/j.mencom.2016.09.019

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