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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2016 Volume 26, Issue 2, Pages 143–145 (Mi mendc2140)

This article is cited in 14 papers

Communications

Covalent binding of fullerene C60 to dithienylethene as a promising approach to the preparation of new photochromic compounds

A. R. Tuktarova, A. A. Khuzina, A. R. Akhmetova, L. M. Khalilova, A. R. Tulyabaeva, V. A. Barachevskiĭb, O. V. Venidiktovab, U. M. Dzhemileva

a Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation
b Photochemistry Center, FSRC ‘Crystallography and Photonics’, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A dithienylethene-containing fullerocyclopropane was synthesized by the catalytic reaction of the carbon cluster with diazoalkane generated in situ by the oxidation of a corresponding photochrome hydrazone with MnO2 in the presence of the Pd(acac)2–2PPh3–4Et3Al catalyst, and the photochromic properties of the synthesized methanofullerene were evaluated.

Language: English

DOI: 10.1016/j.mencom.2016.03.021



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