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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2016 Volume 26, Issue 2, Pages 141–142 (Mi mendc2139)

This article is cited in 5 papers

Communications

Synthesis and X-ray structure of C88(7)(CF3)12/16

N. B. Tamm, S. I. Troyanov

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Compounds C88(7)(CF3)12 and C88(7)(CF3)16 were isolated by HPLC from the trifluoromethylation products of a mixture of C88 isomers. An X-ray diffraction study revealed that the trifluoromethylation patterns are characterized by the additions in edge-sharing para and meta C6(CF3)2 hexagons and the presence of stabilizing isolated and partially isolated C=C bonds on the fullerene cage.

Language: English

DOI: 10.1016/j.mencom.2016.03.020



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