Communications

Charge redistribution in the SpnF-catalyzed Diels–Alder reaction

M. G. Medvedev^ab, F. N. Novikov^a, I. S. Bushmarinov^b, A. A. Zeifman^a, M. S. Polkovnichenko^c, O. V. Stroganov^a, G. G. Chilov^a, K. A. Lyssenko^b, I. Svitanko<sup>a

a</sup> N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^c Moscow State High School No. 192, Moscow, Russian Federation

Abstract: Investigation of charge delocalization (redistribution) in a SpnF-catalyzed reaction that proceeds through overlapping Diels–Alder and bis-pericyclic mechanisms has shown that it is better represented as a nonpolar cycloaddition rather than a cationic rearrangement.

Language: English

DOI: 10.1016/j.mencom.2017.09.024

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