This article is cited in 22 papers

Communications

Magnetic field effect on the oxidation of hydrocarbons by molecular oxygen

E. M. Pliss^a, A. M. Grobov^a, A. K. Kuzaev^a, A. L. Buchachenko<sup>abc

a</sup> P.G. Demidov Yaroslavl State University, Yaroslavl, Russian Federation
^b Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
^c N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Magnetic fields (0.3–0.4 T) were found to accelerate the oxidation of styrene and ethylbenzene with molecular oxygen by 10–70% with increasing the rate of initiation and decreasing the rate of chain termination. The effects are consistently explained in terms of triplet–singlet spin conversion in radical pairs, and they can be used to elucidate the oxidation mechanisms of biologically important molecules (polyunsaturated acids and lipids).

Language: English

DOI: 10.1016/j.mencom.2017.05.009

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