This article is cited in 8 papers

Communications

Zirconium-catalyzed cycloalumination of alkenes in the one-pot synthesis of 3-substituted 1H-phospholane oxides

L. K. Dil'mukhametova, T. V. Tyumkina, V. A. D'yakonov, U. M. Dzhemilev

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Abstract: A new one-pot synthesis of 3-R-1H-phospholane oxides (57–65% yield) was implemented by reaction of phosphorus tri- or pentahalides with 3-R-1-aluminacyclopentanes (in situ generated by Zr-catalyzed cycloalumination of alkenes). The products are readily P-vinylated by Cu-promoted reaction with alkynes.

Language: English

DOI: 10.1016/j.mencom.2017.01.006

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