This article is cited in 6 papers

Communications

An original catalytic synthesis of boriran-1-ols

L. O. Khafizova, L. I. Khusainova, T. V. Tyumkina, K. S. Ryazanov, N. R. Porod'ko, U. M. Dzhemilev

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Abstract: 2-Alkylboriran-1-ols were obtained in a one-pot process by hydrolysis of 1-fluoro- and 1-chloroboriranes in 90–92% yield. The starting 1-haloboriranes were generated by cycloboration of α-olefins with BCl₃·SMe₂ or BF₃·THF in the presence of Mg metal (acceptor of halogen ions) and Cp₂TiCl₂ catalyst.

Language: English

DOI: 10.1016/j.mencom.2018.11.003

Bibliographic databases:

•