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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2024 Volume 34, Issue 4, Pages 552–554 (Mi mendc184)

This article is cited in 2 papers

Communications

The Huisgen’s cycloaddition of BODIPY acetylene and ferrocene azides in supercritical CO2

K. G. Pavlova, D. A. Guka, R. O. Burlutskya, A. A. Moiseevaa, O. O. Krasnovskayaab, D. A. Lemenovskiia, N. V. Zyka, E. K. Beloglazkinaa

a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b National University of Science and Technology 'MISIS', Moscow, Russian Federation

Abstract: The copper-catalyzed azide–alkyne cycloaddition of BODIPY acetylene derivative and ferrocene azides in supercritical CO2 at 80 °C and 81 bar affords the corresponding triazole-containing BODIPY–ferrocene conjugates in high yields. The fluorescent and electrochemical properties of the compounds thus obtained were explored.

Keywords: green chemistry, supercritical fluid, CO2, copper, azide–alkyne cycloaddition.

Language: English

DOI: 10.1016/j.mencom.2024.06.027



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