This article is cited in 2 papers

Communications

Synthesis, structure and magnetic properties of the dinuclear complex [1,3-C₆H₄{NC(Ph)N(SiMe₃)}₂]₃Dy₂ coordinated by ansa-bis(amidinate) ligands with a m-phenylene linker

G. G. Skvortsov^a, A. V. Cherkasov^a, J. Long^b, J. Larionova^b, A. A. Trifonov<sup>ac

a</sup> G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod, Russian Federation
^b Institut Charles Gerhardt Montpellier, UMR-5253 CNRS-UM-ENSCM, Ingenierie Moleculaire et Nano-Objets, Universite de Montpellier, Montpellier Cedex 5, France
^c A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A salt metathesis reaction of anhydrous DyCl₃ and [1,3-C₆H₄{NC(Ph)N(SiMe₃)}₂Li₂(THF)₂] in THF affords the complex [1,3-C₆H₄{NC(Ph)N(SiMe₃)}₂]₃Dy₂ regardless of a ratio between reagents. The assembling of a binuclear core results from a spanning coordination of the amidinate fragments of three μ-bridging ansa-bis(amidinate) ligands to two Dy³⁺ ions. The magnetic properties of the product were studied by SQUID magnetometry in a temperature range of 1.8–300K.

Language: English

DOI: 10.1016/j.mencom.2018.09.024

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