This article is cited in 1 paper

Communications

Novel thiophosphorylated calix[4]resorcinol Mannich bases and their electrochemical behavior in hydrogen evolution reaction

I. R. Mironova (Knyazeva), V. I. Matveeva, V. V. Khrizanforova, Yu. H. Budnikova, A. R. Burilov

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Abstract: Aminomethylation of thiophosphorylated calix[4]resorcinol with formaldehyde and secondary amines affords the novel Mannich base derivatives possessing better solubility. The nickel complex of morpholinomethyl derivative exhibits a good catalytic activity in hydrogen evolution decreasing potential of direct acid reduction on glassy carbon electrode to 1.3V.

Language: English

DOI: 10.1016/j.mencom.2018.09.022

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