This article is cited in 19 papers

Communications

Synthesis, structures and photophysical properties of phosphorus-containing silver 3,5-bis(trifluoromethyl)pyrazolates

A. A. Titov, A. F. Smol'yakov, K. F. Baranova, O. A. Filippov, E. S. Shubina

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Reaction of a trinuclear silver pyrazolate {[3,5-(CF₃)₂Pz]Ag}₃ complex with tricyclohexylphosphine at different reagent ratios leads to the formation of heteroleptic dinuclear or tetranuclear complexes. According to the single crystal X-ray analysis of the dinuclear complex, hexane molecules are incorporated into the cavities formed as the result of supramolecular packing. Coordination of a phosphine ligand makes dinuclear silver pyrazolate to exhibit blue emission at room temperature.

Language: English

DOI: 10.1016/j.mencom.2018.07.015

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