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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2018 Volume 28, Issue 4, Pages 362–363 (Mi mendc1766)

This article is cited in 5 papers

Communications

Synthetically attractive chiral cyclopentenone building blocks conjugated with tetrahydro- and 2-oxotetrahydrofurans

A. Z. Al'mukhametov, A. M. Gimazetdinov, M. S. Miftakhov

Ufa Institute of Chemistry, Ufa Federal Research Centre of the Russian Academy of Sciences, Ufa, Russian Federation

Abstract: Synthetically useful chiral building blocks (3aS,6aR)-1,3,3a,6atetrahydro-4H-cyclopenta[c]furan-4-one and (3aS,6aR)-3a,6a-dihydro-1H-cyclopenta[c]furan-1,4(3H)-dione have been synthesized via a key allylsilane–allyl alcohol fragmentation pathway using (3aS,6S,6aR)-6-(trimethylsilyl)-3,3a,6,6a-tetrahydro-1H-cyclopenta[c]furan-1-one as an illustrative example.

Language: English

DOI: 10.1016/j.mencom.2018.07.006



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