This article is cited in 9 papers

Communications

One-pot two-step stannylation/Stille homocoupling of aryl bromides and iodides under solvent-free conditions

P. S. Gribanov^ab, Yu. D. Golenko^a, M. A. Topchiy^ab, A. N. Philippova^b, N. Yu. Kirilenko^ab, N. V. Krivoshchapov^a, G. K. Sterligov^a, A. F. Asachenko^ab, M. V. Bermeshev^b, M. S. Nechaev<sup>ab

a</sup> Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: A new highly efficient solvent-free method for aryl bromide (iodide) homocoupling comprising the use of Pd(OAc)₂/PCy₃ system in the presence of CsF is suitable for substrates bearing functional groups not tolerant to lithium-, magnesium-, zincorganic reagents and strong bases.

Language: English

DOI: 10.1016/j.mencom.2018.05.032

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