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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2018 Volume 28, Issue 2, Pages 216–218 (Mi mendc1719)

This article is cited in 21 papers

Communications

The features of hydrogen ignition over Pt and Pd foils at low pressures

N. M. Rubtsova, V. I. Chernysha, G. I. Tsvetkova, K. Ya. Troshinb, I. O. Shamshinb, A. P. Kalininc

a A.G. Merzhanov Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
b N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation
c A.Yu. Ishlinsky Institute for Problems in Mechanics, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: In experiments on 2 H2 + O2 ignition over Pd and Pt foils at P0 = 40–180 Torr and T0 = 20–288 °C, it has been shown that the temperature of the initiated ignition over heated Pd foil is ~100 °C lower than that over heated Pt foil; even the minimum temperature is already enough to ignite the mixture. The activity of Pd foil expresses itself both in the dark catalytic reaction and in the occurrence of local ignition centers on the foil, from which combustion wave propagates.

Language: English

DOI: 10.1016/j.mencom.2018.03.037



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