This article is cited in 4 papers

Communications

A novel polybromide complex of bismuth – (Et₄N)₃{[Bi₂Br₉](Br₂)}: synthesis and structural features

S. A. Adonin^ab, I. D. Gorokh^b, P. A. Abramov^ab, I. V. Korolkov^ab, M. N. Sokolov^ac, V. P. Fedin<sup>ab

a</sup> A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation
^b Novosibirsk State University, Novosibirsk, Russian Federation
^c Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

Abstract: The polybromide complex (Et₄N)₃{[Bi₂Br₉](Br₂)} was obtained by reaction of [BiBr₆]^3–, Br₂ and tetraethylammonium bromide in 2 m HBr. In its crystal structure, bioctahedral [Bi₂Br₉]^3– anions are connected by neutral Br₂ linkers into infinite 1D chains via terminal bromide ligands.

Language: English

DOI: 10.1016/j.mencom.2018.01.012

Bibliographic databases:

•