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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2019 Volume 29, Issue 5, Pages 509–511 (Mi mendc1573)

This article is cited in 9 papers

Communications

Ultrafast hydrolytic degradation of 2,3-dihydroxypropyl functionalized poly(ethylene phosphates)

M. A. Kosareva, D. E. Gavrilova, I. E. Nifant'evab, A. V. Shlyakhtina, A. N. Tavtorkinab, V. P. Dyadchenkoa, V. A. Roznyatovskya, P. V. Ivchenkoab

a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: 2,3-Dihydroxypropyl functionalized polyphosphates obtained via controlled acid-catalyzed hydrolysis of 2-[(2,2-dimethyl-1,3-dioxolan-4-yl)methoxy]- or 2-(oxiran-2-ylmethoxy)-1,3,2-dioxaphospholane 2-oxide homopolymers are highly sensitive to basic hydrolysis along the polyphosphate chain.

Language: English

DOI: 10.1016/j.mencom.2019.09.010



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