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JOURNALS // Mendeleev Communications // Archive

Mendeleev Commun., 2019 Volume 29, Issue 2, Pages 212–214 (Mi mendc1475)

This article is cited in 6 papers

Communications

Electrochemical and spectroelectrochemical properties of tetra-tert-butylphthalocyanine indium(III)

E. O. Moiseevaa, Ya. B. Platonovaab, D. V. Konevcd, S. A. Trashinb, L. G. Tomilovaab

a Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
b Institute of Physiologically Active Compounds, Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
c Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation
d D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

Abstract: The known tetra-tert-butylphthalocyanine indium(III) complex was obtained via a novel procedure based on the microwave assisted synthesis, which made it possible to shorten the reaction duration to 5min and to significantly increase the yield. Redox transitions of the obtained complex were characterized by cyclic voltammetry and square-wave voltammetry. The spectroelectrochemical data revealed the opportunity to utilize this complex as an electrochromic component in various devices.

Language: English

DOI: 10.1016/j.mencom.2019.03.033



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