This article is cited in 3 papers

Communications

New preparative Grignard synthesis of (m-carboranylmethyl)siloxanes from chlorodimethylsiloxanes

B. A. Izmaylov, V. A. Vasnev, G. D. Markova

A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Abstract: New m-carborane-containing siloxanes were obtained by the Grignard reaction based on chloromethyl-m-carboranes and chlorodimethylsiloxanes. In case of (7-methyl-m-carboran-1-yl)methyl chloride, side processes of isomerization and transmetalation do not occur, which provides the yield of the desired product as high as 87%.

Language: English

DOI: 10.1016/j.mencom.2019.03.026

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