This article is cited in 20 papers

Communications

Solvent-free Suzuki and Stille cross-coupling reactions of 4- and 5-halo-1,2,3-triazoles

P. S. Gribanov^ab, G. A. Chesnokov^ac, P. B. Dzhevakov^a, N. Yu. Kirilenko^ac, S. A. Rzhevskiy^ac, A. A. Ageshina^c, M. A. Topchiy^ac, M. V. Bermeshev^c, A. F. Asachenko^ac, M. S. Nechaev<sup>ac

a</sup> Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^c A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: An environmentally friendly and efficient synthesis of fully substituted 1,2,3-triazoles comprises solvent-free palladium-catalyzed Suzuki cross-coupling of halo-1,2,3-triazoles with pinacol arylboronates. The efficiencies of Stille and Suzuki reactions with halotriazoles under solvent-free conditions were compared.

Language: English

DOI: 10.1016/j.mencom.2019.03.009

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