This article is cited in 15 papers

Communications

Cyclometallated 1,2,3-triazol-5-ylidene iridium(III) complexes: synthesis, structure, and photoluminescence properties

M. A. Topchiy^a, P. B. Dzhevakov^b, N. Yu. Kirilenko^b, S. A. Rzhevskiy^a, A. A. Ageshina^a, V. N. Khrustalev^cd, D. Yu. Parashchuk^ef, M. V. Bermeshev^a, M. S. Nechaev^ab, A. F. Asachenko<sup>ab

a</sup> A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russian Federation
^b Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^c Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation
^d National Research Centre 'Kurchatov Institute', Moscow, Russian Federation
^e International Laser Center, M. V. Lomonosov Moscow State University, Moscow, Russian Federation
^f Department of Physics, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: A series of heteroleptic cyclometallated 1,2,3-triazol-5-ylidene Ir^III complexes were synthesized and structurally characterized. These new complexes demonstrated photoluminescence in green (550nm) and cyan (499, 496nm) regions. Their photophysical properties were rationalized using DFT calculations.

Language: English

DOI: 10.1016/j.mencom.2019.03.002

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