This article is cited in 1 paper

Communications

Preparation and crystal structure of D_2d-C₈₄(23)Cl₂₄ chlorofullerene

S. I. Troyanov

Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation

Abstract: Chlorofullerene D_2d-C₈₄(23)Cl₂₄ was prepared by chlorination of D_2d-C₈₄(23) with VCl₄ or SbCl₅ at 320–350 °C. An X-ray crystallographic study with the use of synchrotron radiation revealed the addition pattern of 24 Cl atoms stabilized by the formation of isolated C=C bonds and benzenoid rings on the carbon cage.

Keywords: higher fullerenes, C₈₄, chlorination, IPR isomers, structure elucidation.

Language: English

DOI: 10.1016/j.mencom.2024.04.031

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