This article is cited in 7 papers

Communications

Thermal polycondensation of hexakis(p-acetylphenoxy)-cyclotriphosphazene

E. M. Chistyakov^a, M. I. Buzin^b, S. M. Aksenov^bc, A. S. Tupikov^a, V. V. Kireev<sup>a

a</sup> D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^c FSRC “Crystallography and Photonics”, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: The thermal polycondensation of acetophenoxy groups in hexakis(p-acetylphenoxy)cyclotriphosphazene proceeds in two ways, namely, dimerization and trimerization, to produce chalcone or 1,3,5-triarylbenzene moieties, respectively. The polymers formed in both cases are thermally stable up to 400°C. The structure of hexakis(p-acetylphenoxy)cyclotriphosphazene has been established by X-ray study.

Language: English

DOI: 10.1016/j.mencom.2019.01.034

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