This article is cited in 21 papers

Communications

Ammonium iodide-mediated electrosynthesis of unsymmetrical thiosulfonates from arenesulfonohydrazides and thiols

A. O. Terent'ev^ab, O. M. Mulina^a, A. I. Ilovaisky^a, V. A. Kokorekin^ac, G. I. Nikishin<sup>a

a</sup> N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
^c I.M. Sechenov First Moscow State Medical University, Moscow, Russian Federation

Abstract: Unsymmetrical thiosulfonates were synthesized from thiols and arenesulfonohydrazides by their electrolysis in undivided cell equipped with graphite anode and stainless steel cathode under high current density applying NH₄I both as a redox catalyst and a supporting electrolyte. In the course of the process, oxidative formation of S–S bond occurs with the loss of hydrazine moiety.

Language: English

DOI: 10.1016/j.mencom.2019.01.027

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