This article is cited in 2 papers

Communications

Solvent-free silica gel mediated decarboxylation of C–O coupling products of β-diketones and β-oxo esters with malonyl peroxides

O. V. Bityukov^ab, V. A. Vil'^abc, N. V. Lukashin^ac, A. G. Cherednichenko^d, G. I. Nikishin^a, A. O. Terent'ev<sup>abc

a</sup> N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b All-Russian Research Institute of Phytopathology, Bol'shiye Vyazemy, Moscow Region, Russian Federation
^c D.Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation
^d Peoples Friendship University of Russia (RUDN University), Moscow, Russian Federation

Abstract: Silica gel was found to mediate decarboxylation of tetracarbonyl compounds with a free carboxylic group prepared from β-dicarbonyl compounds and malonyl peroxides. Under solvent-free heterogeneous conditions silica gel effectively acts as a mediator of C–O coupling with further decarboxylation at 120°C.

Language: English

DOI: 10.1016/j.mencom.2019.01.017

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