This article is cited in 5 papers

Communications

Reaction of R-pulegone with P–H phosphonium salts

M. E. Shemakhina^ab, A. V. Nemtarev^ab, R. R. Fayzullin^a, N. R. Khasiyatullina^a, L. R. Grigor’eva^b, V. F. Mironov<sup>ab

a</sup> A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
^b Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

Abstract: The reaction of the R-pulegone with P–H-phosphonium salts gives the corresponding 8-phosphonio-p-menthan-3-one salts with high regio- and stereoselectivity. The structure of salts was determined by NMR and IR spectroscopy, mass spectrometry and X-ray diffraction analysis.

Keywords: phosphonium salt, R-pulegone, p-menthane, α,β-enones, terpenes, terpenoids, triphenylphosphine, addition reaction.

Language: English

DOI: 10.1016/j.mencom.2020.11.003

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