This article is cited in 1 paper

Communications

Tris[(pyridin-4-yl)methyl]phosphine, its P-oxide and CuI-based 1D polymer thereof

M. P. Davydova, T. S. Sukhikh, A. V. Artem'ev

A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation

Abstract: Tris[(pyridin-4-yl)methyl]phosphine and its P-oxide, new promising ligands, were obtained based on the reaction between 4-[(trimethylsilyl)methyl]pyridine and PCl₃. The coordination properties of tris[(pyridin-4-yl)methyl]phosphine oxide (L) were exemplified by the synthesis of a braided-shaped chain polymer [Cu₄I₄L₂] showing green luminescence at ambient temperature.

Keywords: tris[(pyridin-4-yl)methyl]phosphine, phosphine oxides, copper(i) complexes, crystal structure, coordination polymers.

Language: English

DOI: 10.1016/j.mencom.2024.04.011

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