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Communications

In situ CO₂ reactivation of FeCrO_x/C catalyst in the oxidative dehydrogenation of ethane to ethylene

I. I. Mishanin^ab, V. I. Bogdan<sup>ab

a</sup> Department of Chemistry, M.V. Lomonosov Moscow State University, Moscow, Russian Federation
^b N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Abstract: Catalyst FeCrO_x/C in the course of oxidative dehydrogenation of ethane with carbon dioxide to ethylene at temperatures of 600–700°C was found to undergo in situ regeneration with CO₂ to give a stoichiometric amount of CO by the Boudoir–Bell reaction with the surface carbonized material.

Keywords: oxidative dehydrogenation, ethane, carbon supports, Fe–Cr oxide catalysts, ethylene, ‘Sibunit’ support.

Language: English

DOI: 10.1016/j.mencom.2020.05.033

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