This article is cited in 4 papers

Communications

Regioselective synthesis of 1-azinyl-1′-isopropenylferrocenes

A. A. Musikhina^ab, I. A. Utepova^ab, O. N. Chupakhin^ab, A. I. Suvorova^b, E. Yu. Zyryanova<sup>b

a</sup> I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation
^b Institute of Chemical Engineering, Ural Federal University, Ekaterinburg, Russian Federation

Abstract: The Friedel–Crafts acetylation (Ac₂O/AlCl₃) reaction of azinylferrocenes occurs regioselectively at position 1′. Acetylated derivatives upon reaction with Ph₃P=CH₂ give the corresponding 1-azinyl-1′-isopropenylferrocenes.

Keywords: ferrocenes, isopropenylferrocene, regioselective synthesis, Friedel–Crafts acylation, Wittig reaction, azines.

Language: English

DOI: 10.1016/j.mencom.2020.03.026

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