This article is cited in 5 papers

Communications

Synthesis and properties of the salts of 1-nitropropan-2-one and 1-nitrobutan-2-one

V. L. Rusinov^ab, R. A. Drokin^a, D. V. Tiufiakov^a, E. K. Voinkov^a, E. N. Ulomsky<sup>ab

a</sup> Institute of Chemical Engineering, Ural Federal University, Ekaterinburg, Russian Federation
^b I.Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, Ekaterinburg, Russian Federation

Abstract: A new safe synthesis of α-nitro ketone salts via alkaline hydrolysis of 2-morpholino-1-nitroalkenes has been developed. The salts were introduced into the reactions of diazotization and heterocyclization. Crystal structures of new 2-morpholino-1-nitrobut-1-ene and 6-ethyl-5-nitro-4phenyl-3,4-dihydropyrimidin-2-one have been determined.

Keywords: nitro compounds, ketones, nitroazine systems, nitroacetone, enamines, diazonium salts, pyrimidinones, hydrazones.

Language: English

DOI: 10.1016/j.mencom.2020.03.015

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