This article is cited in 3 papers

Communications

Hayashi ligand-based rhodium complex in carbon monoxide and molecular hydrogen-assisted reductive amination

S. A. Runikhina^a, D. A. Chusov<sup>ab

a</sup> A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation
^b G.V. Plekhanov Russian University of Economics, Moscow, Russian Federation

Abstract: The CO- and H₂-assisted reductive amination of carbonyl compounds catalyzed by stable chiral Hayashi ligand-based rhodium complex afforded the racemic amines in moderate yields. The racemic outcome of the process results from the elimination of the chiral ligand from the catalyst under the action of hydrogen or carbon monoxide as reductants.

Keywords: chiral complexes, rhodium complexes, reductive amination, carbon monoxide, Hayashi ligand, diene complexes, aldehydes, ketones, amines.

Language: English

DOI: 10.1016/j.mencom.2021.11.004

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