Abstract:
It is established experimentally that the viscosity of micrometer interlayers of mineral motor oil and $n$-hexadecane between metal substrates differs from the viscosity of the isotropic liquid and depends on the shear strain rate. The observed difference is attributed to the formation of orientation-ordered layers in the field of fluctuation forces of the substrates; the thickness of these layers decreases with the intensity of the flow. The results of viscosimetric experiments are interpreted using a rheological model of a structurally inhomogeneous interlayer with “constant-viscosity” surface layers and an isotropic liquid between these layers. This model is employed for calculating the main structural parameters of such layers and the effect of the flow on them.