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Zhurnal Tekhnicheskoi Fiziki, 2025 Volume 95, Issue 9, Pages 1756–1764 (Mi jtf8312)

XXIX Symposium "Nanophysics and Nanoelectronics" in Nizhny Novgorod, March 10-14, 2025
Physics of nanostructures

The method of crystalline nanostructures formation from amorphous vanadium dioxide films

A. I. Komonova, N. D. Mantsurova, B. V. Voloshina, V. A. Selezneva, V. N. Kichaib, L. V. Yakovkinab, S. V. Mutilina

a Rzhanov Institute of Semiconductor Physics, Siberian Branch of Russian Academy of Sciences, Novosibirsk
b Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk

Abstract: This work proposes a precise technique for the vanadium dioxide crystalline nanostructures formation from thin solid amorphous vanadium oxide films grown on silicon substrates. High accuracy of the formed nanoscale structures is achieved via using atomic layer deposition and oxidation scanning probe lithography methods. The amorphous nanostructures undergo crystallization following temperature annealing in vacuum. The size of the formed nanocrystals is defined by the thickness of the initial amorphous film and the geometry of the amorphous nanostructures. In this work we obtained single polycrystalline nanostructures and ordered arrays of nanostructures. Lateral dimensions of crystalline nanostructures are less than 100 nm. The single vanadium dioxide nanocrystals are less than 5 nm in height and less than 50 nm in diameter.

Keywords: atomic layer deposition, oxidation scanning probe lithography, post-growth annealing, vanadium dioxide nanostructures, vanadium dioxide nanocrystals.

Received: 23.04.2025
Revised: 23.04.2025
Accepted: 23.04.2025

DOI: 10.61011/JTF.2025.09.61236.73-25



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