A. A. Artyukh, I. A. Mikhailov, L. A. Chernozatonskii, “Limitations of the fluorination of graphene on a substrate”, Pis'ma v Zh. Èksper. Teoret. Fiz., 2018, Volume 107, Issue 1,Pages <nobr>73

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Limitations of the fluorination of graphene on a substrate

A. A. Artyukh^a, I. A. Mikhailov^b, L. A. Chernozatonskii^ab

^a Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow, Russia
^b Research School Chemistry and Technology of Polymeric Materials, Plekhanov Russian University of Economics, Moscow, Russia

Abstract: The experimentally observed incomplete fluorination of graphene ($\mathrm{CF}_x$, $x\leq0.2{-}0.3$) on a smooth substrate has been explained. It has been shown that fluorine atoms are covalently attached primarily to scanty folds or to defects of graphene on one of its free sides.

Received: 02.11.2017
Revised: 15.11.2017

DOI: 10.7868/S0370274X18010137