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Fizika Tverdogo Tela, 2019 Volume 61, Issue 5, Pages 953–959 (Mi ftt8833)

This article is cited in 1 paper

XVII International Theophilov Symposium, Yekaterinburg, September 23-28, 2018
Optical properties

Rise kinetics of up-conversion luminescence of the LiY$_{0.8}$Yb$_{0.2}$F$_{4}$ : Tm$^{3+}$ (0.2 at.%) crystal with pulsed excitation

A. V. Mikheeva, B. N. Kazakovb

a Kazan State Technological University
b Kazan Federal University

Abstract: The regression analysis of the rise kinetics of up-conversion luminescence of the LiY$_{0.8}$Yb$_{0.2}$F$_{4}$ : Tm$^{3+}$ (0.2 at.%) crystal is performed. The kinetics curve is obtained with rectangular pulsed excitation by radiation from a laser diode (IR LD) with a wavelength of $\lambda_ p$ = 933 nm. The most important—in these experimental conditions—mechanisms of the energy transfer from Yb$^{3+}$ ions to Tm$^{3+}$ ions are established, which are responsible for the transitions between the ground $^{3}$H$_{6}$ and excited $^{3}$F$_{4}$, $^{3}$H$_{4}$,$^{1}$G$_{4}$, $^{1}$D$_{2}$, and $^{1}$I$_{6}$ terms of the Tm$^{3+}$ ions. The durations of the relevant energy transfer processes are determined. It is shown that the energy transfer between rare earth ions in the LiY$_{0.8}$Yb$_{0.2}$F$_{4}$ : Tm$^{3+}$ (0.2 at.%) crystal occurs through the dipole–dipole interactions.

DOI: 10.21883/FTT.2019.05.47601.07F


 English version:
Physics of the Solid State, 2019, 61:5, 860–866

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