Abstract:
The structural stability of stepped Ni(755) and Ni(771) surfaces in the temperature range 20–500$^\circ$C and during adsorption of oxygen and different forms of carbon has been studied using scanning tunneling microscopy and low-energy electron diffraction. A phase transition from the structure with double steps at room temperature to the structure with single steps at a temperature above 350$^\circ$C has been observed on the clean Ni(755) surface. This transition disappears after oxygen adsorption at a temperature above 350$^\circ$C. In this case, the structure on the Ni(755) surface with single steps is stabilized in contrast to Ni(771), which tends to faceting during oxygen adsorption. It has been shown that fullerenes C$_{60}$ form an array of one-dimensional chains at the upper boundaries of steps of the substrate, when they are adsorbed on the Ni(755) surface.