Abstract:
A nanocomposite chrysotile–KDP (KH$_2$PO$_4$) was prepared. KDP was introduced into empty nanochannels of chrysotile asbestos with diameters of $\sim$5 nm. Thermal conductivity $\varkappa$ and heat capacity at a constant pressure $C_p$ of the samples of chrysotile asbestos and nanocomposite chrysotile asbestos–KDP were measured in a temperature range of 80–300 K. Based on the analysis of the behavior of temperature dependences $\varkappa(T)$ and $C_p(T)$ of the composite, temperatures of the ferroelectric transition $T_F$ for KDP in nanochannels of chrysotile asbestos were determined. It turned out to be equal to $\sim$250 K at $T_F$$\sim$122 K for massive KDP samples.