Abstract:
The anisotropy of the optical properties of a single crystal of the hexagonal manganite HoMnO$_3$ has been investigated by spectroscopic ellipsometry in the spectral range 0.6–5.0 eV. It has been demonstrated that the optical absorption edge for the polarization $\mathbf{E}\perp c$ is determined by the intense narrow transition O(2$p$) $\to$ Mn(3$d$) centered at 1.5 eV, whereas this transition for the polarization
$\mathbf{E}\parallel c$ is strongly suppressed and shifted toward higher energies by 0.2 eV. It has been revealed that, at the temperature $T$ = 293 K, the spectra for both polarizations $\mathbf{E}\parallel c$ and $\mathbf{E}\perp c$ exhibit a broad absorption band centered at $\sim$2.4 eV, which was earlier observed in nonlinear spectra during optical second harmonic generation.