Fullerenes

Crystalline complexes of fullerene with anisole derivatives

G. V. Markin, E. V. Baranov, S. Yu. Ketkov, M. A. Lopatin, V. A. Kuropatov, A. S. Shavyrin, G. A. Domrachev

G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod

Abstract: For the first time, bis(anisole)chromium fulleride (PhOMe)$_2$Cr$^{+\bullet}$[C$_{60}$]$^{-\bullet}$ and a crystalline complex of fullerene with ortho-butoxyanisole have been obtained. The temperature dependence of the parameters of the EPR spectrum of bis(anisole)chromium fulleride (PhOMe)$_2$Cr$^{+\bullet}$[C$_{60}$]$^{-\bullet}$ has been studied. The molecular structure of the complex of fullerene with ortho-butoxyanisole has been established.

Received: 19.07.2011
Accepted: 05.09.2011

 English version: Physics of the Solid State, 2012, 54:3, 647–651

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