This article is cited in 9 papers

Phase transitions

Phase diagram and thermodynamic equilibrium in the Fe$_x$TiSe$_2$ system

E. G. Shkvarina, V. A. Tsurin, A. N. Titov, S. G. Titova, O. M. Fedorova

Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences, Ekaterinburg

Abstract: Phase diagram has been refined by the quenching method; the phase composition has been monitored by NGR spectroscopy. The experimental data agree well with theoretical predictions on the relation of the phase diagram with the character of a chemical bond. It has been shown that the system is essentially nonquasi-binary because of the selenium exchange between the precipitated iron and the matrix lattice.

Received: 26.07.2011

 English version: Physics of the Solid State, 2012, 54:3, 626–629

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