Abstract:
The short-range order in amorphous SiO$_x$ (0 $\le x\le$ 2) films has been studied by high-resolution X-ray photoelectron spectroscopy. Both the random bonding and random mixture models do not describe experimental photoelectron spectra of SiO$_x$ ($x\le$ 2). An intermediate model of the SiO$_x$ structure has been proposed. The measured photoelectron spectra of the SiO$_x$ ($x\le$ 2) valence band indicate the presence of the silicon phase and silicon oxide.