Abstract:
Using the controlled selenization method, CuInSe$_2$ films with a chalcopyrite structure were synthesized. It was established that the selenization temperature $(T_{\mathrm{sel}})$ is a critical parameter determining the morphology and electrophysical properties of the films. A nonlinear volt-ampere characteristic was found, caused by the electrical inhomogeneity of the material. The optimum $T_{\mathrm{sel}}$ = 350$^\circ$C was determined, at which the maximum photoelectric effect and the longest relaxation time are observed. At $T_{\mathrm{sel}}<$ 300$^\circ$C, a photoinduced change in impedance was detected.