Abstract:
The kinetics of structural phase transformations in quasicrystal-forming Al–Cu–Fe alloys with compositions in the region of stability of the icosahedral $(\iota)$ phase has been investigated. It has been shown that, depending on the development of metastable transformations $\iota\to$ pentagonal phases $P1$ and $P2$, a homogeneous lamellar structure $(\iota + P1 + P2)$ or a polygrain $\iota$-phase is formed in the alloys. The $P$–$h$ diagrams obtained upon nanoindentation, atomic force microscopy, and scanning electron microscopy of indentations have demonstrated signs of elasto-plastic deformation of the alloys with lamellar and polygrain icosahedral structures. It has been found that, in contrast to the polygrain icosahedral alloys with a normal size effect of nanoindentation, the alloys with a lamellar structure are characterized by a nonmonotonic dependence of the hardness $(H)$ on the maximum load $(P_{\mathrm{\max}})$ and exhibit the effect of strain hardening in the range of loads 50 mN $\le P_{\mathrm{\max}}<$ 500 mN. The strain hardening is considered as the result of resistance exerted by boundaries of the lamellar structure to the development of plastic deformation.