Abstract:
The phase composition and morphology of the twin structure of the Y$_2$Î$_3$-stabilized zirconia crystals (from 2.8 to 4.0 mol%) after the thermal treatment at 1600$^\circ$C have been investigated by X-ray diffractometry and transmission electron microscopy. It is shown that as the concentration of the stabilizing Y$_2$Î$_3$ impurity increases, the character of the twin structure changes, and the amount of the untransformed phase $t'$ increases. The dependence of the hardness and crack resistance of the crystals of partially stabilized zirconia on the Y$_2$Î$_3$ concentration and the indenter orientation is investigated using the microindentation method. The sample with the lowest concentration of the stabilizing Y$_2$Î$_3$ impurity turned out the most crack resistant. This can be explained by a high content of tetragonal phase $t$ in it, which provides the transformation strengthening mechanism of the material, and by a more multilevel character of twinning.