Abstract:
A detailed analysis of the correlation between the volumetric thermal expansion coefficient o$(T)$ and heat capacity $C(T)$ of a rare-gas (Ar) cryocrystal has been performed. It has been shown that there is a clear correlation dependence o$(C)$ not only in the low-temperature range, where it is linear and known as the Grüneisen law, but also in a significantly wider temperature range (up to the melting point of argon). The dependence o$(C)$ substantially deviates from the low-temperature linear behavior when the heat capacity reaches the classical Dulong–Petit limit of 3$R$.