Abstract:
The electron paramagnetic resonance (EPR) spectra of Eu$^{2+}$ impurity centers in SrMoO$_4$ crystals have been studied in the temperature range of 1.8, 100–300 K. A hyperfine structure has been simulated for 151,153Eu of different EPR transitions observed experimentally at different temperatures and external magnetic field orientations. A unique set of all parameters of the spin Hamiltonian for the known sign of the hyperfine interaction parameters $A_i$ has been determined. It has been found that the diagonal parameters $|b_n^0|$ of the spin Hamiltonian decrease with increasing temperature; however, the parameter $b_4^4$ increases. The results of the study have demonstrated that $|b_2^0(T)/P_2^0(T)\sim\operatorname{const}$ for Eu$^{151,153}$ in this single crystal.