Abstract:
The study of the dielectric properties of a CdIn$_2$S$_4$$\langle$3 mol% Cu$\rangle$ single crystal in alternating-current (ac) electric fields with frequencies $f$ = 5 $\times$ 10$^4$ – 3.5 $\times$ 10$^7$ Hz has revealed the origin of dielectric loss (relaxation loss that is changed by the through current loss at high frequencies). It has been found that CdIn$_2$S$_4$$\langle$Cu$\rangle$ has permittivity increment $\Delta\varepsilon'$ = 123, relaxation frequency $f_r$ = 2.3 $\times$ 10$^4$ Hz, and relaxation time $\tau$ = 43 $\mu$s. The doping of CdIn$_2$S$_4$ single crystal with copper (3 mol%) is established to substantially increase the permittivity $(\varepsilon')$, dielectric loss tangent $(\tan\delta)$, and ac conductivity $(\sigma_{\mathrm{ac}})$. In this case, the frequency dispersion of $\varepsilon'$ and $\tan\delta$ increases and that of $\sigma_{\mathrm{ac}}$ decreases.