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Fizika Tverdogo Tela, 2025 Volume 67, Issue 5, Pages 797–799 (Mi ftt11490)

Semiconductors

Electrically inactive magnesium in silicon

V. B. Shuman, A. N. Lodygin, A. A. Yakovleva, L. M. Portsel'

Ioffe Institute, St. Petersburg

Abstract: The dynamics of MgO complex formation during magnesium diffusion in Czochralskii-grown silicon with oxygen content of $\sim$ 3 $\cdot$ 10$^{17}$ cm$^{-3}$ has been studied. MgO complexes were found to form only at temperatures above 1100$^\circ$C. At lower temperatures, magnesium atoms are in a bound state, presumably in the form of particles, or Mg$_2$Si phase. The formation of complexes occurs after the dissociation of Mg$_2$Si into Mg and Si at higher temperatures. Thus, the experimental results confirm the assumption that the electrically inactive component of the magnesium content in the crystal is the Mg$_2$Si compound.

Received: 29.04.2025
Revised: 29.04.2025
Accepted: 29.04.2025

DOI: 10.61011/FTT.2025.05.60740.97-25



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© Steklov Math. Inst. of RAS, 2026