Abstract:
X-ray diffraction and differential scanning calorimetry have been used to study changes in the lattice parameters and Neel temperature of the compounds GdMn$_2$(Ge$_{1-x}$Si$_x$)$_2$ ($x$ = 0–1) with increasing Si content. It is shown that substitution of Ge by Si leads to an 8% decrease in the unit cell volume of the compounds at room temperature. It is found that the Neel temperature of the compounds increases with increasing Si content from 365 K at $x$ = 0 to 465 K at $x$ = 1. The magnetic phase diagram of the system GdMn$_2$(Ge$_{1-x}$Si$_x$)$_2$ is constructed according to the obtained data.
Keywords:rare-earth intermetallics, magnetic phase transitions, magnetic phase diagram, X-ray diffraction, differential scanning calorimetry.